Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/1823
Título: | Sol-gel derived Li+-doped poly(ε-caprolactone)/siloxane biohybrid electrolytes |
Autor(es): | Nunes, Sílvia Zea Bermudez, V. de Silva, Maria Manuela Smith, Michael John Morales, Enrique Carlos, Luís Ferreira, R. A. Sá Rocha, João |
Palavras-chave: | Sol-gel Poly(e-caprolactone)/siloxane hybrid Ionic conductivity Thermal stability poly(epsilon-caprolactone)/siloxane hybrid Poly(ε-caprolactone)/siloxane hybrid |
Data: | 2006 |
Editora: | Springer |
Revista: | Journal of Solid State Electrochemistry |
Resumo(s): | Electrolytes based on a poly(ε-caprolactone) (PCL)/siloxane organic/inorganic host framework doped with lithium triflate (LiCF3SO3) were synthesised through the sol-gel process. In this biohybrid matrix short PCL chains are covalently bonded via urethane linkages to the siliceous network. Samples with salt composition n (molar ratio of PCL repeat units per Li+ ion) ranging from ∞ to 0.5 were investigated. All the ormolyte materials analysed are amorphous. Xerogels with n > 0.5 are thermally stable up to about 300°C. The most conducting ormolyte of the series is that with n = 0.5 (1.6×10−7 and 3.2×10−5 Ω−1 cm−1 at 25 and 100°C, respectively). This sample is electrochemically stable between −1 and 6 V versus Li+. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/1823 |
DOI: | 10.1007/s10008-005-0651-0 |
ISSN: | 1432-8488 |
Versão da editora: | The original publication is available at www.springerlink.com (DOI 10.1007/s10008-005-0651-0) |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
JSSE05.pdf | 464,06 kB | Adobe PDF | Ver/Abrir |