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https://hdl.handle.net/1822/92220| Título: | Cooling rate uncovers epimer-dependent supramolecular organization of carbohydrate amphiphiles |
| Autor(es): | Castro, Vânia I. B. Gao, Yuting Brito, Alexandra Chen, Jie Reis, R. L. Pashkuleva, I. Pires, R. A. |
| Palavras-chave: | Carbohydrates Helicity Isomers Nanofibers Self-assembly Supramolecular polymerization |
| Data: | Jun-2024 |
| Editora: | Royal Society of Chemistry |
| Revista: | Journal of Materials Chemistry B |
| Citação: | Castro V. I. B., Gao Y., Brito A., Chen J., Reis R. L., Pashkuleva I., Pires R. A. Cooling rate uncovers epimer-dependent supramolecular organization of carbohydrate amphiphiles, Journal Of Materials Chemistry B, pp. in press, 2050-7518, 2024 |
| Resumo(s): | We show distinct CH-pi interactions and assembly pathways for the amphiphile N-(fluorenylmethoxycarbonyl)-galactosamine and its epimer N-(fluorenylmethoxycarbonyl)-glucosamine. These differences result in the formation of supramolecular nanofibrous systems with opposite chirality. Our results showcase the importance of the carbohydrates structural diversity for their specific biointeractions and the opportunity that their ample interactome offers for synthesis of versatile and tunable supramolecular (bio)materials. |
| Tipo: | Artigo |
| URI: | https://hdl.handle.net/1822/92220 |
| ISSN: | 2050-7518 |
| Versão da editora: | https://doi.org/10.1039/D4TB00728J |
| Arbitragem científica: | yes |
| Acesso: | Acesso aberto |
| Aparece nas coleções: |
Ficheiros deste registo:
| Ficheiro | Descrição | Tamanho | Formato | |
|---|---|---|---|---|
| 21203-d4tb00728j.pdf | 2,24 MB | Adobe PDF | Ver/Abrir |
