Utilize este identificador para referenciar este registo: https://hdl.handle.net/1822/63828

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dc.contributor.authorMacedo, A. S.por
dc.contributor.authorCarvalho, Estelapor
dc.contributor.authorCardoso, V. F.por
dc.contributor.authorCorreia, D. M.por
dc.contributor.authorTubio, C. R.por
dc.contributor.authorFidalgo-Marijuan, A.por
dc.contributor.authorBotelho, Gabrielapor
dc.contributor.authorLanceros-Méndez, S.por
dc.date.accessioned2020-02-10T08:57:36Z-
dc.date.issued2020-
dc.identifier.citationMacedo, A. S.; Carvalho, Estela; Cardoso, V. F.; Correia, D. M.; Tubio, C. R.; Fidalgo-Marijuan, A.; Botelho, G.; Lanceros-Méndez, S., Tailoring electroactive poly(vinylidene fluorideco-trifluoroethylene) microspheres by a nanoprecipitation method. Materials Letters, 261(127018), 2020por
dc.identifier.issn0167-577Xpor
dc.identifier.urihttps://hdl.handle.net/1822/63828-
dc.description.abstractPoly(vinylidene fluorideco-trifluoroethylene) (P(VDF-TrFE)) microspheres were obtained by a nanoprecipitation method based on the deposition of a polymeric solution over a non-solvent (NS) solution. The effect of several parameters on sphere formation was evaluated, including copolymer concentration, NS content (methanol/water ratio) and surfactant type. Morphological and physico-chemical characterizations were performed. Depending on processing conditions, spheres with diameters ranging from ~100 to 1100nm with similar physico-chemical properties were obtained. Independently of the processing conditions, P(VDF-TrFE) microspheres crystallize in the electroactive phase with an average crystallinity of 26%. Thus, samples show the required characteristics for biomedical applications.por
dc.description.sponsorshipFundação para a Ciência e Tecnologia (FCT); UID/FIS/04650/2019, UID/EEA/04436/2019, PTDC/BTM-MAT/28237/2017, PTDC/EMDEMD/28159/2017 and POCI-01-0145-FEDER-028159. FCT is also acknowledged by E.O.C. and D.M.C. for the grants SFRH/BD/145455/2019 and SFRH/BPD/121526/2016, respectively. The Spanish Ministry of Economy and Competitiveness (MINECO): project MAT2016-76039-C4-3-R (AEI/FEDER, UE). Basque Government Industry and Education Departments: ELKARTEK, HAZITEK and PIBA.por
dc.language.isoengpor
dc.publisherElsevier 1por
dc.relationUID/FIS/04650/2019por
dc.relationUID/EEA/04436/2019por
dc.relationPTDC/BTM-MAT/28237/2017por
dc.relationPTDC/EMDEMD/28159/2017por
dc.relationSFRH/BD/145455/2019por
dc.relationSFRH/BPD/121526/2016por
dc.rightsrestrictedAccesspor
dc.subjectMicrospherespor
dc.subjectNanoprecipitationpor
dc.subjectElectroactivepor
dc.subjectP(VDF-TrFE)por
dc.titleTailoring electroactive poly(vinylidene fluorideco-trifluoroethylene) microspheres by a nanoprecipitation methodpor
dc.typearticle-
dc.peerreviewedyespor
dc.relation.publisherversionhttps://www.journals.elsevier.com/materials-letterspor
dc.commentsCEB52312por
oaire.citationVolume261por
dc.date.updated2020-01-12T12:43:09Z-
dc.identifier.doi10.1016/j.matlet.2019.127018por
dc.date.embargo10000-01-01-
dc.description.publicationversioninfo:eu-repo/semantics/publishedVersion-
dc.subject.wosScience & Technologypor
sdum.journalMaterials Letterspor
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CDQuim - Artigos (Papers)

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