Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/59170

TitleInfluence of acid on the photoredox reaction between tris(2,2′-bipyridyl)ruthenium(II) and iron(III)
Author(s)Ferreira, Maria Isabel Pereira Lucas Calado
Harriman, Anthony
Issue date1979
JournalJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
CitationJ. Chem. Soc., Faraday Trans. 2, 1979,75, 874-879
Abstract(s)Photoreaction between (bipy) 3 Ru 2+ (1) and iron(III) leads to efficient, reversible electron transfer. The rates of forward and reverse electron transfers are somewhat dependent upon the structure of the iron species. The forward reaction is fastest with the simple hydrated iron(III) ion but the reverse reaction is fastest when the iron(III) species is a negatively charged complex ion. Also, the concentration of acid is important and high concentrations of perchloric and trifluoromethyl-sulphonic acids yield the highest steady-state yield of redox products.
Typearticle
URIhttp://hdl.handle.net/1822/59170
DOI10.1039/F29797500874
ISSN0300-9238
Peer-Reviewedyes
AccessrestrictedAccess
Appears in Collections:CDQuim - Artigos (Papers)

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