Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/49902
Título: | d-Poly(e-caprolactone) (530)/siloxane biohybrid films doped with protic ionic liquids |
Autor(es): | Fernandes, M. Cardoso, M. A. Rodrigues, L. C. Silva, Maria Manuela Ferreira, R. A. S. Carlos, L. D. Nunes, S. C. de Zea Bermudez, V. |
Palavras-chave: | Poly(ε-caprolactone)/siloxane hybrid N-Ethylimidazolium trifluoromethanesulfonate N-Butylimidazolium trifluoromethanesulfonate Structure Morphology Ionic conductivity Poly(e-caprolactone)/siloxane hybrid |
Data: | 2017 |
Editora: | Elsevier 1 |
Revista: | Journal of Electroanalytical Chemistry |
Resumo(s): | Organic/inorganic biohybrids composed of poly(ε-caprolactone) (PCL(530)) (where 530 represents the average molecular weight of the chains in gmol−1 ) chains covalently bonded to a siloxane network via urethane linkages and incorporating protic ionic liquids (PILs) were investigated. The materials (H-PILX, where H represents the host hybrid matrix and X is the ratio, in %, of the mass of PIL per mass of organic precursor) were doped with two different concentrations of N-ethylimidazolium trifluoromethanesulfonate ([EIm][TfO]) and N-butylimidazolium trifluoromethanesulfonate ([BIm][TfO]). The samples were processed as essentially amorphous and transparent films, thermally stable up to at least 200 °C. The highest ionic conductivity value (4.3 × 10−5 S cm−1 ) was measured for H-[EIm][TfO]16.4 at 105 °C. This work emphasizes that Scanning Electron Microscopy (SEM)/Energy Dispersive X-ray Spectroscopy (EDS) measurements are mandatory for the morphological characterization of IL-based electrolytes. In the case of the most concentrated [BIm][TfO]-doped hybrid studied this technique enabled the detection of segregated silica-rich circular micro-sized regions formed as a result of the hydrophobic interactions established between the bulky butyl chains of the [BIm]+ cation and the PCL(530) chains of the host matrix. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/49902 |
DOI: | 10.1016/j.jelechem.2017.06.009 |
ISSN: | 1572-6657 |
e-ISSN: | 1873-2569 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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J. Electroanalytical Chemistry M. Fernandes et al (2017).pdf | 1,97 MB | Adobe PDF | Ver/Abrir |