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https://hdl.handle.net/1822/46559
Título: | Carbon and MnO₂ materials on carbon nanofibers cotton textile substrate for hybrid solid-state supercapacitors |
Autor(es): | Lufrano, Francesco Vieito, António Jose Paleo Brigandì, Antonino Ferreira, Fernando Rocha, A. M. Staiti, Pietro |
Data: | 2017 |
Resumo(s): | This work is focused on the design and development of hybrid solid-state energy storage devices with high capacitive performance. In particular, the work includes, the preparation of carbon composite electrodes based on a carbon nanofibers (CNF) supported on a cotton fabric. The coating of CNF to the cotton cloth is obtained by the dip and dry method. On these so-obtained composite substrates, further layers of activated carbon (Norit A Supra Eur) and manganese oxide (MnO2) material have been subsequenlty deposited to enhance the electrochemical performances of negative and positive electrodes, respectively. The preparation of carbon-based active layers comprises the spreading on the negative CNF-substrate of a slurry containing the activated carbon (AC) material, graphite fibres and polyvinylidene difluoride (PVDF) in N,N dimethylacetamide (DMA). Whereas the positive electrode is prepared by spreading a slurry of MnO2, carbon black, graphite fibers, PVDF in DMA. A 1M Na2SO4 solution impregnated in the porous paper separator (Nippon Kodoshi Corportion, Japan) and a polymer electrolyte membrane (Nafion 115) have been employed as electrolytes. The different supercapacitors were electrochemically characterized by cyclic voltammetry (CV), galvanostatic charge/discharge (G–CD), electrochemical impedance spectroscopy (EIS) and long-term cycling stability tests. The hybrid carbon-based textile supercapacitors exhibited capacitance performance of 137 and 120 F/g with the porous separator and Nafion 115 membrane, respectively. Specially, the solid-state (Nafion membrane) hybrid device demonstrated very long stability in cycling (10000 cycles) and holding voltage condition at 1.6 V (more than 100 h). Besides, these textile-based capacitors also showed slow self-discharge. |
Tipo: | Comunicação em painel |
URI: | https://hdl.handle.net/1822/46559 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | DET/2C2T - Comunicações em congressos internacionais com arbitragem científica |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Abstract ISEECap2017.pdf | 255,55 kB | Adobe PDF | Ver/Abrir |