Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/42862
Título: | High performance screen-printed electrodes prepared by a green solvent approach for lithium-ion batteries |
Autor(es): | Gören, Attila Mendes, Jorge António Silva Rodrigues, H.M. Sousa, R. Oliveira, J. Hilliou, L. Costa, Carlos Miguel Silva Silva, Maria Manuela Lanceros-Méndez, S. |
Palavras-chave: | C-LFP Graphite DMPU solvent Rheological properties Screen-printing technique Lithium-ion batteries |
Data: | Dez-2016 |
Editora: | Elsevier |
Revista: | Journal of Power Sources |
Citação: | Gören, A., Mendes, J., Rodrigues, H. M., et. al.(2016). High performance screen-printed electrodes prepared by a green solvent approach for lithium-ion batteries. Journal of Power Sources, 334, 65-77 |
Resumo(s): | New inks based on lithium iron phosphate and graphite for cathode and anode, respectively, were developed for printable lithium-ion batteries using the “green solvent” N,N′-dimethylpropyleneurea (DMPU) and poly(vinylidene fluoride), PVDF, as a binder. The results were compared with the ones from inks developed with the conventionally used solvent N-methyl-2-pyrrolidone, NMP. The rheological properties of the PVDF/DMPU binder solution shows a more pronounced shear thinning behavior than the PVDF/NMP solution. Cathode inks prepared with 2.25 mL and 2.50 mL of DMPU for 1 g of electrode mass show an apparent viscosity of 3 Pa s and 2 Pa s for a shear rate of 100 s−1, respectively, being therefore processable by screen-printing or doctor blade techniques. The electrodes prepared with DMPU and processed by screen-printing show a capacity of 52 mAh g−1 at 2C for the cathode and 349 mAh g−1 at C/5 for the anode, after 45 charge-discharge cycles. The electrochemical performance of both electrodes was evaluated in a full-cell and after 9 cycles, the discharge capacity value is 81 mAh g−1, showing a discharge capacity retention of 64%. The new inks presented in this work are thus suitable for the development of printed batteries and represent a step forward towards more environmental friendly processes. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/42862 |
DOI: | 10.1016/j.jpowsour.2016.10.019 |
ISSN: | 0378-7753 |
Versão da editora: | http://www.sciencedirect.com/science/article/pii/S037877531631401X |
Arbitragem científica: | yes |
Acesso: | Acesso restrito UMinho |
Aparece nas coleções: | IPC - Artigos em revistas científicas internacionais com arbitragem |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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jpowersource 2016 NMPgreen.pdf Acesso restrito! | 2,09 MB | Adobe PDF | Ver/Abrir |
Este trabalho está licenciado sob uma Licença Creative Commons