Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/22660
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Campo DC | Valor | Idioma |
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dc.contributor.author | Cardoso, Paulo | - |
dc.contributor.author | Silva, J. | - |
dc.contributor.author | Paiva, M. C. | - |
dc.contributor.author | Hattum, F. W. J. van | - |
dc.contributor.author | Lanceros-Méndez, S. | - |
dc.date.accessioned | 2013-01-16T14:38:08Z | - |
dc.date.available | 2013-01-16T14:38:08Z | - |
dc.date.issued | 2012 | - |
dc.identifier.citation | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS Volume: 50 Issue: 17 Pages: 1253-1261 DOI: 10.1002/polb.23110 Published: SEP 1 2012 | - |
dc.identifier.issn | 0887-6266 | por |
dc.identifier.uri | https://hdl.handle.net/1822/22660 | - |
dc.description.abstract | The electrical properties and dispersion of vapor-grown carbon nanofibers (VGCNF) and multi-walled carbon nanotubes (MWCNT) - epoxy resin composites are studied and compared. A blender was used to disperse the nanofillers within the matrix, producing samples with concentrations of 0.1, 0.5 and 1.0 wt.% for both nanofillers, besides the neat sample. The dispersion of the nanofillers was qualitatively analyzed using scanning electron microscopy (SEM), transmission optical microscopy (TOM) and greyscale analysis (GSA). The electrical conductivity and the dielectric constant were evaluated. The percolation threshold of MWCNT epoxy composites is lower than 0.1 wt.% while for VGCNF lies between 0.1 and 0.5 wt.%. The difference on the dispersion ability of the two nanofillers is due to their intrinsic characteristics. Celzard’s theory is suitable to calculate the percolation threshold bounds for the VGCNF composites but not for the MWCNT composites, indicating that intrinsic characteristics of the nanofillers beyond the aspect ratio are determinant for the MWCNT composites electrical conductivity. | por |
dc.description.sponsorship | Foundation for Science and Technology, Lisbon, for financial support through the 3 degrees Quadro Comunitario de Apoio, the POCTI and FEDER programmes, projects PTDC/CTM/69316/2006, PTDC/CTM-NAN/112574/2009, and NANO/NMed-SD/0156/2007, and grants SFRH/BD/41191/2007 (P. C.) and SFRH/BD/60623/2009 (J.S.). The authors thank Albermarle for the hardener, Hexion Specialty Chemicals for the epoxy resin, and Nanocyl for providing the MWCNT. Also thank the COST actions MP1003 "European Scientific Network for Artificial Muscles" (ESNAM) and MP0902 "Composites of Inorganic Nanotubes and Polymers (COINAPO)" for their support. | por |
dc.language.iso | eng | por |
dc.publisher | Wiley-Blackwell | por |
dc.rights | restrictedAccess | por |
dc.subject | dispersion | por |
dc.subject | electrical properties | por |
dc.subject | epoxy resin | por |
dc.subject | fillers | por |
dc.subject | MWCNT | por |
dc.subject | nanocomposites | por |
dc.subject | percolation threshold | por |
dc.subject | thermosets | por |
dc.subject | VGCNF | por |
dc.title | Comparative analyses of the electrical properties and dispersion level of VGCNF and MWCNT: epoxy composites | por |
dc.type | article | por |
dc.peerreviewed | yes | por |
sdum.publicationstatus | published | por |
oaire.citationStartPage | 1253 | por |
oaire.citationEndPage | 1261 | por |
oaire.citationIssue | 17 | por |
oaire.citationVolume | 50 | por |
dc.identifier.doi | 10.1002/polb.23110 | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | Journal of Polymer Science Part B: Polymer Physics | por |
Aparece nas coleções: | CDF - FCD - Artigos/Papers (with refereeing) IPC - Artigos em revistas científicas internacionais com arbitragem |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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JPS_B_PP_2012.pdf Acesso restrito! | 1,05 MB | Adobe PDF | Ver/Abrir |