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https://hdl.handle.net/1822/1767
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Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Nunes, Sílvia | - |
dc.contributor.author | Zea Bermudez, V. de | - |
dc.contributor.author | Ostrovskii, David | - |
dc.contributor.author | Silva, Maria Manuela | - |
dc.contributor.author | Barros, Sandra Cerqueira | - |
dc.contributor.author | Smith, Michael John | - |
dc.contributor.author | Carlos, Luís | - |
dc.contributor.author | Rocha, João | - |
dc.contributor.author | Morales, Enrique | - |
dc.date.accessioned | 2005-05-24T12:00:17Z | - |
dc.date.available | 2005-05-24T12:00:17Z | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | "Journal of the electrochemical society". 152 (2005) 429-438. | eng |
dc.identifier.issn | 0013-4651 | por |
dc.identifier.uri | https://hdl.handle.net/1822/1767 | - |
dc.description.abstract | Poly(oxyethylene)( POE)/siloxane hybrids (di-ureasils) doped with a wide concentration range of lithium triflate were investigated. The host matrix of these materials (d-U(2000)) is a sol-gel derived siliceous network to which POE chains with about 40 repeat units are bonded through urea linkages. Xerogels with n between 500 and 5 (where n is the molar ration of OCH2CH2 repeat units to lithium íons) were obtained as amorphous monoliths thermally stable up to at least 340ºC. A crystalline POE/LiCF3SO3 complex was detected spectroscopically in samples with compositions of n less than 10. Below 90ºC the ormolyte with n = 20 exhibits the highest ionic conductivity of the series characterized. The redox stability of this material is about 4.1 volts. | eng |
dc.language.iso | eng | eng |
dc.publisher | Electrochemical Society | por |
dc.rights | openAccess | eng |
dc.subject | Sol-gel synthesis | eng |
dc.subject | Ionic conductivity | eng |
dc.subject | Thermal analysis | eng |
dc.subject | Solid polymer electrolytes | eng |
dc.title | Di-urea cross-linked poly(oxyethylene)/siloxane ormolytes for lithium batteries | eng |
dc.type | article | eng |
dc.peerreviewed | yes | eng |
oaire.citationStartPage | A429 | por |
oaire.citationEndPage | A438 | por |
oaire.citationIssue | 2 | por |
oaire.citationVolume | 152 | por |
dc.identifier.doi | 10.1149/1.1851051 | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | Journal of the Electrochemical Society | por |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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JELSoc.pdf | Main article with figures | 1,12 MB | Adobe PDF | Ver/Abrir |