Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/16786

TitleSelective recovery of copper, nickel and zinc from ashes produced from Saccharomyces cerevisiae contaminated biomass used in the treatment of real electroplating effluents
Author(s)Machado, Manuela D.
Soares, Eduardo V.
Soares, Helena M. V. M.
KeywordsChemical precipitation
Chemical speciation
Electrolysis
Heavy metals recovery
Incineration
Issue date2010
PublisherElsevier
JournalJournal of Hazardous Materials
Abstract(s)The aim of this work was to seek an environmentally friendly process for recycling metals from biomass-sludges generated in the treatment of industrial wastewaters. This work proposes a hybrid process for selective recovery of copper, nickel and zinc from contaminated biomass of Saccharomyces cerevisiae, used in the bioremediation of electroplating effluents. The developed separation scheme comprised five consecutive steps: (1) incineration of the contaminated biomass; (2) microwave acid (HCl) digestion of the ashes; (3) recovery of copper from the acid solution by electrolysis at controlled potential; (4) recycle of nickel, as nickel hydroxide, by alcalinization of the previous solution at pH 14; (5) recovery of zinc, as zinc hydroxide, by adjusting the pH of the previous solution at 10. This integrated approach allowed recovering each metal with high yielder (>99% for all metals) and purity (99.9%, 92% and 99.4% for copper, nickel and zinc, respectively). The purity of the metals recovered allows selling them in the market or being recycled in the electroplating process without waste generation.
TypeArticle
URIhttp://hdl.handle.net/1822/16786
DOI10.1016/j.jhazmat.2010.08.044
ISSN0304-3894
Publisher versionhttp://www.sciencedirect.com/
Peer-Reviewedyes
AccessRestricted access (UMinho)
Appears in Collections:CEB - Publicações em Revistas/Séries Internacionais / Publications in International Journals/Series

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