Solid polymer electrolytes based on gellan gum and ionic liquid for sustainable electrochromic devices

Abstract

Materials sustainability is becoming increasingly relevant in every developed technology and, consequently, environmentally friendly solid polymer electrolytes (SPEs) based on gellan gum and different quantities of ionic liquid (IL) 1- Ethyl-3-methyl-imidazolium-thiocyanate [Emim][SCN] have been prepared and applied in electrochromic devices (ECDs). The addition of the IL does not affect the crystalline phase of gellan gum and the samples show a compact morphology, surface uniformity, no phase separation and good distribution of the IL within the carrageenan matrix. The developed SPE are thermally stable up to ~ 100 ºC and show suitable mechanical properties. The most concentrated sample (39 wt.% IL content) reaches a maximum ionic conductivity value of 6.010–3 S cm–1 and 1.810–2 S cm–1 at 30 ºC and 90 ºC, respectively. The electrochromic device (ECD) was fabricated with poly(3,4- ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) as working electrode and the developed SPE was compared with an aqueous 0.1 M KNO3 solution. The electrochromic performance of the electrolyte was assessed in terms of spectroelectrochemistry, demonstrating a fully flexible ECD operating at voltages below 1.0 V. This novel electrolyte opens the door to the preparation of high performance sustainable ECD.