Analysis and design of a silicide-tetrahedrite thermoelectric generator concept suitable for large-scale industrial waste heat recovery

Abstract

Industrial Waste Heat Recovery (IWHR) is one of the areas with strong potential for energy efficiency and emissions reductions in industry. Thermoelectric (TE) generators (TEGs) are among the few technologies that are intrinsically modular and can convert heat directly into electricity without moving parts, so they are nearly maintenance-free and can work unattended for long periods of time. However, most existing TEGs are only suitable for small-scale niche applications because they typically display a cost per unit power and a conversion efficiency that is not competitive with competing technologies, and they also tend to rely on rare and/or toxic materials. Moreover, their geometric configuration, manufacturing methods and heat exchangers are often not suitable for large-scale applications. The present analysis aims to tackle several of these challenges. A module incorporating constructive solutions suitable for upscaling, namely, using larger than usual TE elements (up to 24 mm in diameter) made from affordable p-tetrahedrite and n-magnesium silicide materials, was assessed with a multiphysics tool for conditions typical of IWHR. Geometric configurations optimized for efficiency, power per pair and power density, as well as an efficiency/power balanced solution, were extracted from these simulations. A balanced solution provided 0.62 kWe/m² with a 3.9% efficiency. Good prospects for large-scale IWHR with TEGs are anticipated if these figures could be replicated in a real-world application and implemented with constructive solutions suitable for large-scale systems.