Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/48262
Título: | L-alaninium perrhenate: crystal structure and non-linear optical properties |
Autor(es): | Rodrigues, Vitor H. Costa, Maria M. R. R. Gomes, Etelvina M. Isakov, Dmitry Belsley, M. |
Palavras-chave: | Amino acids Perrhenic acid Second-harmonic generation X-ray diffraction Crystal engineering |
Data: | 2014 |
Editora: | Walter de Gruyter GmbH |
Revista: | Central European Journal of Chemistry |
Resumo(s): | The crystal structure and non-linear optical properties of L-alaninium perrhenate, C3H8NO2+ ReO4 (-), are reported. The protonated amino acid and the perrhenate anion have their usual geometries. The three-dimensional hydrogen-bonded network can be seen as a stacking of layers parallel to the (100) planes. Each layer is formed by chains of alternating positive and negative ions along the b and c axes. Hydrogen bonding of adjacent layers forms alternating chains along the a axis. A high damage threshold and a second-harmonic generation efficiency three times that of KDP make this new material potentially useful in non-linear optics. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/48262 |
DOI: | 10.2478/s11532-014-0548-9 |
ISSN: | 1895-1066 |
e-ISSN: | 1644-3624 |
Arbitragem científica: | yes |
Acesso: | Acesso restrito UMinho |
Aparece nas coleções: | CDF - FAMO - Artigos/Papers (with refereeing) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Lalaninium perrhenate.pdf Acesso restrito! | 848,32 kB | Adobe PDF | Ver/Abrir |