Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/43682
Registo completo
Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Driest, P. J. | por |
dc.contributor.author | Lenzi, V. | por |
dc.contributor.author | Marques, L. | por |
dc.contributor.author | Ramos, M. M. D. | por |
dc.contributor.author | Dijkstra, D. J. | por |
dc.contributor.author | Richter, F. U. | por |
dc.contributor.author | Stamatialis, D. | por |
dc.contributor.author | Grijpma, D. W. | por |
dc.date.accessioned | 2016-12-22T15:56:49Z | - |
dc.date.available | 2016-12-22T15:56:49Z | - |
dc.date.issued | 2017 | - |
dc.identifier.citation | Driest, P. J., Lenzi, V., Marques, L. S. A., Ramos, M. M. D., Dijkstra, D. J., Richter, F. U., Stamatialis, D., and Grijpma, D. W. (2017) Aliphatic isocyanurates and polyisocyanurate networks. Polym. Adv. Technol., doi: 10.1002/pat.3891. | por |
dc.identifier.issn | 1099-1581 | por |
dc.identifier.uri | https://hdl.handle.net/1822/43682 | - |
dc.description.abstract | The production, processing, and application of aliphatic isocyanate (NCO)-based thermosets such as polyurethane coatings and adhesives are generally limited by the surprisingly high viscosity of tri-functionality and higher-functionality isocyanurates. These compounds are essential crosslinking additives for network formation. However, the mechanism by which these high viscosities are caused is not yet understood. In this work, model aliphatic isocyanurates were synthesized and isolated in high purity (>99%), and their viscosities were accurately determined. It was shown that the presence of the NCO group has a strong influence on the viscosity of the system. From density functional theory calculations, a novel and significant bimolecular binding potential of À8.7 kJ/mol was identified be- tween NCO groups and isocyanurate rings, confirming the important role of the NCO group. This NCO-to-ring inter- action was proposed to be the root cause for the high viscosities observed for NCO-functional isocyanurate systems. Molecular dynamics simulations carried out to further confirm this influence also suggest that the NCO-to- ring interaction causes a significant additional contribution to viscosity. Finally, model functional isocyanurates were further reacted into densely crosslinked polyisocyanurate networks which showed interesting material properties. | por |
dc.description.sponsorship | This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement no. 642890 (http:// thelink-project.eu/), and it was partially supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the strategic funding UID/FIS/04650/2013, and under the project Search-ON2: NORTE-07-0162-FEDER000086. | por |
dc.language.iso | eng | por |
dc.publisher | John Wiley and Sons | por |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/642890/EU | por |
dc.relation | info:eu-repo/grantAgreement/FCT/5876/147414/PT | por |
dc.rights | openAccess | por |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | por |
dc.subject | Isocyanates | por |
dc.subject | Isocyanurates | por |
dc.subject | Viscosity | por |
dc.subject | Density functional calculations | por |
dc.subject | Network formation | por |
dc.title | Aliphatic isocyanurates and polyisocyanurate networks | por |
dc.type | article | por |
dc.peerreviewed | yes | por |
dc.relation.publisherversion | http://onlinelibrary.wiley.com/doi/10.1002/pat.3891/full | por |
sdum.publicationstatus | info:eu-repo/semantics/publishedVersion | por |
oaire.citationStartPage | 1299 | por |
oaire.citationEndPage | 1304 | por |
oaire.citationIssue | 10 | por |
oaire.citationTitle | Polymers for Advanced Technologies | por |
oaire.citationVolume | 28 | por |
dc.identifier.doi | 10.1002/pat.3891 | por |
dc.subject.fos | Ciências Naturais::Ciências Físicas | por |
dc.subject.fos | Ciências Naturais::Ciências Químicas | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | Polymers for Advanced Technologies | por |
Aparece nas coleções: | CDF - FCT - Artigos/Papers (with refereeing) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
pat3891.pdf | 265,12 kB | Adobe PDF | Ver/Abrir |
Este trabalho está licenciado sob uma Licença Creative Commons