Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/60540

TitlePhotocatalytic performance of N-doped TiO2nano-SiO2-HY nanocomposites immobilized over cotton fabrics
Author(s)Landi Jr., Salmon
Carneiro, Joaquim
Soares, Olivia S. G. P.
Pereira, Manuel F. R.
Gomes, Andreia C
Ribeiro, Artur
Fonseca, António
Parpot, Pier
Neves, Isabel C.
KeywordsPhotocatalysis
Textile functionalization
TiO-SiO
HY zeolite
Rhodamine B
Cytotoxic
TiO2-SiO2
TiO -SiO 2 2
Issue date2019
PublisherElsevier
JournalJournal of Materials Research and Technology
CitationLandi, Salmon; Carneiro, Joaquim; Soares, Olivia S. G. P.; Pereira, Manuel F. R.; Gomes, Andreia C.; Ribeiro, Artur; Fonseca, António; Parpot, Pier; Neves, Isabel C., Photocatalytic performance of N-doped TiO2nano-SiO2-HY nanocomposites immobilized over cotton fabrics. Journal of Materials Research and Technology, 8(2), 1933-1943, 2019
Abstract(s)This work reports the synthesis of nanocomposite photocatalytic materials based on nitrogen-doped TiO2nano, SiO2 and different percentages of HY zeolite (0, 12, 25 and 50%). These materials were characterized by using Fourier transformed infrared spectroscopy, X-ray diffraction, N2 adsorptiondesorption, UV-vis diffuse reflectance spectroscopy and scanning electron microscopy. The nanocomposites, which presented an energy band gap of about 3.03 eV, were immobilized on cotton fabric and their self-cleaning properties were investigated by decolourization of rhodamine B (RhB) dye in aqueous solution under simulated solar irradiation. The fabrics coated with the photocatalysts, containing and not containing zeolites, showed the same RhB decolourization (about 95%) after 5 h, excluding the situation where a large amount of HY (50%) was used in the nanocomposites. However, results obtained from high performance liquid chromatography analysis depicted that in the presence of the HY zeolite a more effective RhB degradation was achieved. In fact, even after the use of five consecutive cycles, the RhB decolourization remained high (about 85%). Generally, the photodegradation of RhB solution in the presence of cotton fabrics functionalized with TiO2nano, TiO2nano-SiO2 and TiO2nano-SiO2-0.25 HY resulted in the formation of products that exhibited a similar cytotoxic effect when compared to the untreated RhB solution and subjected to the same tested concentrations and incubation times.
TypeArticle
URIhttp://hdl.handle.net/1822/60540
DOI10.1016/j.jmrt.2018.06.025
ISSN22387854
Peer-Reviewedyes
AccessOpen access
Appears in Collections:CEB - Publicações em Revistas/Séries Internacionais / Publications in International Journals/Series
CDQuim - Artigos (Papers)

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