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|Title:||BODIPY derivatives: synthesis and evaluation of their optical properties|
|Author(s):||Gonçalves, Raquel C. R.|
Nogueira, Mariana B.
Costa, Susana P. G.
Raposo, M. Manuela M.
|Citation:||Gonçalves, R.; Nogueira, M.; Costa, S. P. G.; Raposo, M. M. M.; BODIPY derivatives: synthesis and evaluation of their optical properties. Proceedings of the 22nd International Electronic Conference on Synthetic Organic Chemistry 1 a 30 de novembro de 2018, Sciforum Electronic Conferences Series, doi: 10.3390/ecsoc-22-05700.|
|Abstract(s):||Three BODIPY derivatives functionalized at meso and 2 position were synthesized in 22-59% yield. The compounds were characterized by the usual spectroscopic techniques and a photophysical study was also undertaken. The BODIPY derivatives presented absorption bands in the 494-512 nm range and were also emissive with fluorescence bands in the 512-514 nm interval. A preliminary study on the sensing ability of BODIPY functionalized at position 2 with a benzimidazole was carried out in acetonitrile and acetonitrile/water (75:25) solutions in the presence of anions and cations with environmental, biomedical and analytical relevance. A highly selective response was obtained for Hg2+ and Fe3+ in acetonitrile/water solution.|
|Appears in Collections:||CDQuim - Comunicações e Proceedings|
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