Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/50719

TitleDesign, synthesis and characterization of novel thienylpyridazine derivatives for optical applications
Author(s)Fernandes, S. S. M.
Raposo, M. Manuela M.
KeywordsPush-pull pi–conjugated systems
Thiophene
Pyridazine
Optical applications
Suzuki coupling
Synthesis
Heterocycles
UV-vis
Fluorescence
Indole
Issue date2016
PublisherMDPI
CitationFernandes, S. S. M.; Raposo, M. M. M. Design, synthesis and characterization of novel thienylpyridazine derivatives for optical applications. 20th Int. Electron. Conf. Synth. Org. Chem., 1–30 November 2016; Sciforum Electronic Conference Series, Vol. 20, 2016, a006.
Abstract(s)In recent years, push-pull π-conjugated systems bearing electron rich (thiophene, pyrrole, furan) and electron deficient heterocycles (pyridine, pyridazine, benzothiazole, etc.) have been widely used as NLO and photochromic materials, metal free organic sensitizers for DSSCs, OLEDs, etc. due to their easy synthesis and efficient tuning of the photophysical properties through small structural modifications.1-2 During the last decade our research group has published experimental and theoretical results concerning the auxiliary donor/acceptor effect of electron rich and electron deficient heterocycles on –conjugated systems.2 Based on our earlier work we were motivated to extend these studies in order to explore the potential application of a new series of donor-acceptor substituted thienylpyridazines in which the pyridazine heterocycle plays the dual role of -bridge and acceptor/auxiliary acceptor moiety. Therefore, the pyridazine ring was functionalized in position 3 with different (hetero)aryl-based groups (indole, benzonitrile and nitrophenyl) in order to study the effect of their electronic nature on the optical properties of the push-pull systems. We report in this work the synthesis and the photophysical characterization of novel thienylpyridazine derivatives which were synthesized through Suzuki coupling of 3-bromo-6-(thiophen-2-yl)pyridazine3 with commercially available (hetero)aryl-boronic acids.
TypeAbstract
URIhttp://hdl.handle.net/1822/50719
Peer-Reviewedyes
AccessOpen access
Appears in Collections:CDQuim - Comunicações e Proceedings

Files in This Item:
File Description SizeFormat 
Sciforum Electronic Conference Series, Vol. 20, 2016, a006-comunication abstract.pdf2.pdfSciforum Electronic Conference Series, Vol. 20, 2016, a006-comunication abstract100,4 kBAdobe PDFView/Open

Partilhe no FacebookPartilhe no TwitterPartilhe no DeliciousPartilhe no LinkedInPartilhe no DiggAdicionar ao Google BookmarksPartilhe no MySpacePartilhe no Orkut
Exporte no formato BibTex mendeley Exporte no formato Endnote Adicione ao seu ORCID