Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/40509

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dc.contributor.authorXiaoman Zhaopor
dc.contributor.authorBansode, Sneha Ramraopor
dc.contributor.authorRibeiro, Artur J.por
dc.contributor.authorAbreu, Ana S.por
dc.contributor.authorOliveira, Césarpor
dc.contributor.authorParpot, Pierpor
dc.contributor.authorGogate, P. R.por
dc.contributor.authorRathod, V. K.por
dc.contributor.authorPaulo, Artur Cavacopor
dc.date.accessioned2016-02-24T11:33:07Z-
dc.date.available2016-02-24T11:33:07Z-
dc.date.issued2016-
dc.identifier.citationZhao, X.; Bansode, Sneha Ramrao; Ribeiro, Artur J.; Abreu, Ana S.; Oliveira, César; Parpot, Pier; Gogate, P. R.; Rathod, V. K.; Paulo, Artur Cavaco, Ultrasound enhances lipase-catalyzed synthesis of poly (ethylene glutarate). Ultrasonics Sonochemistry, 31, 506-511, 2016por
dc.identifier.issn1350-4177por
dc.identifier.urihttp://hdl.handle.net/1822/40509-
dc.description.abstractThe present work explores the best conditions for the enzymatic synthesis of poly (ethylene glutarate) for the first time. The start-up materials are the liquids; diethyl glutarate and ethylene glycol diacetate, without the need of addition of extra solvent. The reactions are catalyzed by lipase B from Candida antarctica immobilized on glycidyl methacrylate-ter-divinylbenzene-ter-ethylene glycol dimethacrylate at 40 °C during 18 h in water bath with mechanical stirring or 1 h in ultrasonic bath followed by 6 h in vacuum in both the cases for evaporation of ethyl acetate. The application of ultrasound significantly intensified the polyesterification reaction with reduction of the processing time from 24 to 7 h. The same degree of polymerization was obtained for the same enzyme loading in less time of reaction when using the ultrasound treatment. The degree of polymerization for long-term polyesterification was improved approximately 8-fold due to the presence of sonication during the reaction. The highest degree of polymerization achieved was 31, with a monomer conversion of 96.77%. The ultrasound treatment demonstrated to be an effective green approach to intensify the polyesterification reaction with enhanced initial kinetics and high degree of polymerization.por
dc.description.sponsorshipThis study was supported by Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UID/BIO/04469/2013 unit and COMPETE 2020 (POCI-01-0145-FEDER-006684). The work was also supported by Bioprocess and Bionanotechnology Research Group (BBRG) of Minho University and the Post Graduate Funding Program of Jiangnan University for Overseas Study. All authors also acknowledge the funding of Department of Science and Technology and Portuguese Science Foundation under the Indo-Portuguese collaborative program.por
dc.language.isoengpor
dc.publisherElsevier B.V.por
dc.relationinfo:eu-repo/grantAgreement/FCT/5876/147337/PTpor
dc.rightsopenAccesspor
dc.subjectUltrasoundpor
dc.subjectLipasepor
dc.subjectSolvent-free synthesispor
dc.subjectPoly (ethylene glutarate)por
dc.subjectKineticspor
dc.titleUltrasound enhances lipase-catalyzed synthesis of poly (ethylene glutarate)por
dc.typearticle-
dc.peerreviewedyespor
dc.relation.publisherversionhttp://www.journals.elsevier.com/ultrasonics-sonochemistry/por
dc.commentsCEB34796por
sdum.publicationstatuspublishedpor
oaire.citationStartPage506por
oaire.citationEndPage511por
oaire.citationConferencePlaceNetherlands-
oaire.citationTitleUltrasonics Sonochemistrypor
oaire.citationVolume31por
dc.date.updated2016-02-21T12:02:53Z-
dc.identifier.essn1350-4177-
dc.identifier.doi10.1016/j.ultsonch.2016.02.005por
dc.identifier.pmid26964978por
dc.subject.wosScience & Technologypor
sdum.journalUltrasonics Sonochemistrypor
Appears in Collections:CEB - Publicações em Revistas/Séries Internacionais / Publications in International Journals/Series
CDQuim - Artigos (Papers)

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