Utilize este identificador para referenciar este registo: http://hdl.handle.net/1822/40359

TítuloProperties and thermal behavior of natural deep eutectic solvents
AutorCraveiro, R.
Aroso, Ivo Manuel Ascensão
Flammia, V.
Carvalho, T.
Viciosa, M. T.
Dionísio, M.
Barreiros, S.
Reis, R. L.
Duarte, Ana Rita C.
Paiva, A.
Palavras-chaveCholine chloride
Conductivity
Deep eutectic eolvents
Physical properties
Thermal analysis
Data2016
EditoraElsevier
CitaçãoCraveiro R., Aroso I. M., Flammia V., Carvalho T., Viciosa M. T., Dionísio M., Barreiros S., Reis R. L., Duarte A. R. C., Paiva A. Properties and thermal behavior of natural deep eutectic solvents, Journal Of Molecular Liquids, Vol. 215, pp. 534-540, doi:10.1016/j.molliq.2016.01.038, 2016
ResumoNatural deep eutectic solvents (NADES) have shown to be promising sustainable media for a wide range of applications. Nonetheless, very limited data is available on the properties of these solvents. A more comprehensive body of data on NADES is required for a deeper understanding of these solvents at molecular level, which will undoubtedly foster the development of new applications. NADES based on choline chloride, organic acids, amino acids and sugars were prepared, and their density, thermal behavior, conductivity and polarity were assessed, for different NADES compositions. The NADES studied can be stable up to 170 Â°C, depending on their composition. The thermal characterization revealed that all the NADES are glass formers and some, after water removal, exhibit crystallinity. The morphological characterization of the crystallizable materials was performed using polarized optical microscopy which also provided evidence of homogeneity/phase separation. The conductivity of the NADES was also assessed from 0 to 40 Â°C. The more polar, organic acid-based NADES presented the highest conductivities. The conductivity dependence on temperature was well described by the Vogelâ Fulcherâ Tammann equation for some of the NADES studied.
Tipoarticle
URIhttp://hdl.handle.net/1822/40359
DOI10.1016/j.molliq.2016.01.038
ISSN0167-7322
Versão da editorahttp://www.sciencedirect.com/science/article/pii/S0167732215303019
Arbitragem científicayes
AcessorestrictedAccess
Aparece nas coleções:3B’s - Artigos em revistas/Papers in scientific journals

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