Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/40326

TitleLaccase-catalyzed synthesis of conducting polyaniline-lignosulfonate composite
Author(s)Zhang, Ya
Dong, Aixue
Fan, Xuerong
Wang, Qiang
Zhang, Ying
Yu, Yuanyuan
Cavaco-Paulo, Artur
KeywordsApplications
Biosynthesis of polymers
Conducting polymers
Issue date5-Feb-2016
PublisherJohn Wiley and Sons
JournalJournal of Applied Polymer Science
CitationZhang, Ya; Dong, Aixue; Fan, Xuerong; Wang, Qiang; Zhang, Ying; Yu, Yuanyuan; Paulo, Artur Cavaco, Laccase-catalyzed synthesis of conducting polyaniline-lignosulfonate composite. Journal of Applied Polymer Science, 133(5), 2016
Abstract(s)Enzymatic polymerization of aniline was first performed in lignosulfonate (LGS) template system. High-redox-potential catalyst laccase, isolated from Aspergillus, was used as a biocatalyst in the synthesis of conducting polyaniline/lignosulfonate (PANI-ES-LGS) complex using atmospheric oxygen as the oxidizing agent. The linear templates (LGS), also serving as the dopants, could facilitate the directional alignment of the monomer and improve the solubility of the conducting polymer. The process of the polymerization was monitored using UV-Vis spectroscopy, by which the conditions for laccase-catalyzed synthesis of PANI-ES-LGS complex were also optimized. The structure characterizations and solubility of the complex were carried out using corresponding characterization techniques respectively. The PANI-ES-LGS suspensions obtained was used as coating for cotton with a conventional padder to explore the applications of the complex. The variable optoelectronic properties of the coated cotton were confirmed by cyclic voltammetry and color strength test. The molecular weight changes of LGS treated by laccase were also studied to discuss the mechanism of laccase catalyzed aniline polymerization in LGS template system.
TypeArticle
URIhttp://hdl.handle.net/1822/40326
DOI10.1002/app.42941
ISSN0021-8995
e-ISSN1097-4628
Publisher versionhttp://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1097-4628
Peer-Reviewedyes
AccessOpen access
Appears in Collections:CEB - Publicações em Revistas/Séries Internacionais / Publications in International Journals/Series

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