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dc.contributor.authorMaceiras, A.por
dc.contributor.authorCosta, C. M.por
dc.contributor.authorLopes, A. C.por
dc.contributor.authorSan Sebastián, M.por
dc.contributor.authorLaza, J. M.por
dc.contributor.authorVilas, J. L.por
dc.contributor.authorRibelles, J. L. G.por
dc.contributor.authorSabater i Serra, R.por
dc.contributor.authorAndrio Balado, A.por
dc.contributor.authorLanceros-Méndez, S.por
dc.contributor.authorLeón, L. M.por
dc.identifier.citationMaceiras, A., Costa, C. M., Lopes, A. C., San Sebastián, M., Laza, J. M., Vilas, J. L., . . . León, L. M. (2015). Dielectric relaxation dynamics of high-temperature piezoelectric polyimide copolymers. Applied Physics A: Materials Science and Processing. doi: 10.1007/s00339-015-9251-8por
dc.description.abstractPolyimide co-polymers have been prepared based on different diamines as co-monomers: a diamine without CN groups and a novel synthesized diamine with two CN groups prepared by polycondensation reaction followed by thermal cyclodehydration. Dielectric spectroscopy measurements were performed and the dielectric complex function, ac conductivity and electric modulus of the co-polymers were investigated as a function of CN group content in the frequency range from 0.1 Hz to 107 Hz at temperatures from 25 to 260 °C. For all samples and temperatures above 150ºC, the dielectric constant increases with increasing temperature due to increaseing conductivity. The α-relaxation is just detected for the sample without CN groups, being this relaxation overlapped by the electrical conductivity contributions in the remaining samples. For the copolymer samples and the polymer with CN groups an important Maxwell-Wagner-Sillars contribution is detected. The mechanisms responsible for the dielectric relaxation, conduction process and electric modulus response have been discussed as a function of the CN groups content present in the samples.por
dc.description.sponsorshipThis work was supported by FEDER through the COMPETE Program and by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Project PESTC/FIS/UI607/2011 and grants SFRH/BD/ 62507/2009 (A.C.L.) SFRH/BD/68499/2010 (C.M.C.). The authors also thank funding from “Matepro – Optimizing Materials and Processes”, ref. NORTE-07-0124-FEDER-000037”, co-funded by the “Programa Operacional Regional do Norte” (ON.2 – O Novo Norte), under the “Quadro de Referência Estratégico Nacional” (QREN), through the “Fundo Europeu de Desenvolvimento Regional” (FEDER). RSS acknowledge the support of the Spanish Ministry of Economy and Competitiveness through the project MAT2012-38359-C03-01 (including the FEDER financial support). Authors also thank the Basque Country Government for financial support (ACTIMAT project, ETORTEK Program, IE13-380, and Ayudas para Grupos de Investigación del Sistema Universitario Vasco Program, IT718-13).por
dc.publisherSpringer Verlagpor
dc.relationSFRH/BD/ 62507/2009por
dc.subjectDielectric responsepor
dc.subjectElectric moduluspor
dc.subjectPolyimides polymerpor
dc.titleDielectric relaxation dynamics of high-temperature piezoelectric polyimide copolymerspor
dc.subject.fosCiências Naturais::Ciências Físicaspor
dc.subject.wosScience & Technologypor
sdum.journalApplied Physics A: Materials Science and Processingpor
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