Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/32183

TitleSynthesis of new benzo[a]phenoxazinium probes possessing carboxylic ester, hydroxyl and amino functional groups: photophysical studies in dry ethanol and conjugation with CdTe quantum dots
Author(s)Raju, B. Rama
Garcia, Arlindo M. Fontes
Costa, A. L. S.
Coutinho, Paulo J. G.
Gonçalves, M. Sameiro T.
KeywordsNile Blue
Benzo[a]phenoxazinium dyes
CdTe quantum dots
Cationic dyes
Near-infrared fluorescent probes
Fluorescent dyes
Issue date2014
PublisherElsevier
JournalDyes and Pigments
Abstract(s)A new series of benzo[a]phenoxazinium chlorides possessing hydroxyl, ethyl ester and amino functional groups as terminal substituents at the 9- and 5-positions of the tetracyclic aromatic system in different combinations, was synthesised. A photophysical study was carried out in anhydrous ethanol and water, as a function of solution pH. Acid dissociation constants were estimated and found to depend on the nature of the terminal groups. Experimental evidence for an additional molecular form is presented and is compatible with J-aggregates of the deprotonated form of some of the earlier studied the benzo[a]phenoxazinium chlorides. The benzo[a]phenoxazinium chloride possessing the amino terminal group was reacted with the carboxylic acid of CdTe quantum dots (QDs) to obtain a conjugate of the dye and QD. Initial photophysical characterisation indicates both photoinduced electron and energy transfer between the QD and the attached benzo[a]phenoxazinium chloride.
TypeArticle
URIhttp://hdl.handle.net/1822/32183
DOI10.1016/j.dyepig.2014.04.006
ISSN0143-7208
Publisher versionhttp://www.sciencedirect.com/science/article/pii/S014372081400134X
Peer-Reviewedyes
AccessRestricted access (UMinho)
Appears in Collections:CDQuim - Artigos (Papers)

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