Utilize este identificador para referenciar este registo: http://hdl.handle.net/1822/31929

TítuloCyanide and fluoride colorimetric sensing by novel imidazo-anthraquinones functionalized with indole and carbazole
Autor(es)Batista, Rosa Maria Ferreira
Oliveira, Elisabete
Costa, Susana P. G.
Lodeiro, Carlos
Raposo, M. Manuela M.
Palavras-chaveImidazole
Anthraquinone
Fluoride
Cyanide
Aqueous media
Naked-eye detection
Data2014
EditoraTaylor & Francis
RevistaSupramolecular Chemistry
Resumo(s)Novel imidazo-anthraquinones functionalized with indole and carbazole have been synthesised and characterised and their evaluation as colorimetric chemosensors was carried out in acetonitrile as well as in acetonitrile/H2O (97:3) in the presence of several anions such as F-, Cl-, Br-, I-, CN-, NO3-, ClO4-, AcO-, BzO-, NO3-, ClO4-, HSO4- and H2PO4-. Additionally, their behaviour in the presence of H+ and OH- was also studied. Upon addition of CN- and F− to acetonitrile solutions of compounds 1-3, a marked colour change from yellow to orange was observed and the fluorescence emission of 1 and 2 was switched “on”. The recognition in organic aqueous solution lead to the selective and sensitive naked-eye detection (mM) of CN- for all receptors, with an easily detectable colour change from yellow to orange. The binding stoichiometry between the receptors and the anions was found to be 2:1. The binding process was also followed by 1H NMR titrations showing that two different binding modes occurred in the presence of fluoride or cyanide anions, which is in agreement with the spectrophotometric titrations.
Tipoarticle
URIhttp://hdl.handle.net/1822/31929
DOI10.1080/10610278.2013.824082
ISSN1061-0278
Versão da editorahttp://www.tandfonline.com/doi/abs/10.1080/10610278.2013.824082#.VIINDosqKfU
Arbitragem científicayes
AcessoopenAccess
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