Please use this identifier to cite or link to this item:
https://hdl.handle.net/1822/31231| Title: | 11, 11, 12, 12-Tetracyano-4, 5-pyrenoquinodimethanes: air-stable push–pull o-Quinodimethanes with S2 fluorescence |
| Author(s): | García, Raúl More, Sandeep Melle-Franco, M. Mateo-Alonso, Aurelio |
| Issue date: | 2014 |
| Publisher: | American Chemical Society |
| Journal: | Organic Letters |
| Abstract(s): | The synthesis and properties of 11,11,12,12-tetracyano-4,5-pyrenoquinodimethanes (4,5-TCNPs), a new family of isolable and air-stable o-quinodimethanes, are reported. The ortho disposition of the dicyanomethane substituents strongly polarizes the pyrene framework to promote broad and intense intramolecular charge-transfer transitions. In addition, spectroscopic studies reveal that 4,5-TCNPs violate Kasha’s rule and emit from the S2 level. |
| Type: | Article |
| URI: | https://hdl.handle.net/1822/31231 |
| DOI: | 10.1021/ol5029332 |
| ISSN: | 1523-7060 |
| Peer-Reviewed: | yes |
| Access: | Restricted access (UMinho) |
| Appears in Collections: |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| koke_organic_letters_ol5029332.pdf Restricted access | ON-Line version (November 2014) | 685,41 kB | Adobe PDF | View/Open |
