Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/3112

TitleElectroreductive cyclisation of unsatured halides catalysed by nickel macrocyclic complexes
Author(s)Duñach, E.
Esteves, Ana Paula
Freitas, A. M.
Medeiros, Maria José
Olivero, S.
KeywordsElectrochemical reactions
Cyclisation
Nickel and compounds
Radicals
Radical reaction
nickel
nickel compounds
Issue date1999
PublisherPergamon-Elsevier Science Ltd
JournalTetrahedron Letters
Citation"Tetrahedron Letters". 40 (1999) 8693-8696.
Abstract(s)The indirect electroreduction of unsaturated aliphatic halides using Ni(II) complexes as electron-transfer mediators is achieved in N,N'-dimethylformamide by constant current electrolysis between a cathode and a sacrificial anode in a diaphragmless cell. Cyclic compounds are obtained in low to high yields in conditions that avoid the usual preparation using organotin reagents.
TypeArticle
URIhttp://hdl.handle.net/1822/3112
DOI10.1016/S0040-4039(99)01845-6
ISSN0040-4039
Peer-Reviewedyes
AccessRestricted access (UMinho)
Appears in Collections:CDQuim - Artigos (Papers)

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