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http://hdl.handle.net/1822/3062
Title: | The study of nickel(II) and cobalt(II) complexes with a chiral salen derivative as catalysts for the electrochemical cyclisation of unsaturated 2-bromophenyl ethers |
Author(s): | Duñach, E. Esteves, Ana Paula Medeiros, Maria José Pletcher, Derek Olivero, S. |
Keywords: | Cyclic voltammetry Electrosynthesis [Ni(salen)] [Co(salen)] Bromophenyl ethers Cyclisation 2-Bromophenyl ethers 2-broniophenyl ethers |
Issue date: | 2004 |
Publisher: | Elsevier Science SA |
Journal: | Journal of Electroanalytical Chemistry |
Citation: | "Journal of Electroanalytical Chemistry". ISSN 0022-0728. 566 (2004) 39–45. |
Abstract(s): | Reductions of Ni(II) and Co(II) complexes with the Jacobsen ligand (a chiral, substituted salen) in the absence and in the presence of allyl 2-bromophenyl ethers in N,N’-dimethylformamide were investigated with the aid of cyclic voltammetry and constant-current and controlled-potential electrolyses. The complexes were effective catalysts for the reduction of these organic substrates and cyclic compounds were obtained in good yields under appropriate experimental conditions. Modest asymmetric induction was observed. |
Type: | Article |
URI: | http://hdl.handle.net/1822/3062 |
DOI: | 10.1016/j.jelechem.2003.10.045 |
ISSN: | 0022-0728 |
Publisher version: | Available online at www.sciencediretc.com |
Peer-Reviewed: | yes |
Access: | Restricted access (UMinho) |
Appears in Collections: | CDQuim - Artigos (Papers) |
Files in This Item:
File | Description | Size | Format | |
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Artigo.pdf Restricted access | Documento principal | 227,96 kB | Adobe PDF | View/Open |