Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/3062

TitleThe study of nickel(II) and cobalt(II) complexes with a chiral salen derivative as catalysts for the electrochemical cyclisation of unsaturated 2-bromophenyl ethers
Author(s)Duñach, E.
Esteves, Ana Paula
Medeiros, Maria José
Pletcher, Derek
Olivero, S.
KeywordsCyclic voltammetry
Electrosynthesis
[Ni(salen)]
[Co(salen)]
Bromophenyl ethers
Cyclisation
2-Bromophenyl ethers
2-broniophenyl ethers
Issue date2004
PublisherElsevier Science SA
JournalJournal of Electroanalytical Chemistry
Citation"Journal of Electroanalytical Chemistry". ISSN 0022-0728. 566 (2004) 39–45.
Abstract(s)Reductions of Ni(II) and Co(II) complexes with the Jacobsen ligand (a chiral, substituted salen) in the absence and in the presence of allyl 2-bromophenyl ethers in N,N’-dimethylformamide were investigated with the aid of cyclic voltammetry and constant-current and controlled-potential electrolyses. The complexes were effective catalysts for the reduction of these organic substrates and cyclic compounds were obtained in good yields under appropriate experimental conditions. Modest asymmetric induction was observed.
TypeArticle
URIhttp://hdl.handle.net/1822/3062
DOI10.1016/j.jelechem.2003.10.045
ISSN0022-0728
Publisher versionAvailable online at www.sciencediretc.com
Peer-Reviewedyes
AccessRestricted access (UMinho)
Appears in Collections:CDQuim - Artigos (Papers)

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