Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/25526

TitleOhmic heating as a new efficient process for organic synthesis in water
Author(s)Pinto, Joana
Silva, Vera L. M.
Silva, Ana M. G.
Silva, Artur M. S.
Costa, José C. S.
Santos, Luís M. N. B. F.
Enes, Roger
Cavaleiro, José A. S.
Vicente, A. A.
Teixeira, J. A.
Issue date2013
PublisherRoyal Society of Chemistry
JournalGreen chemistry
Abstract(s)A new and efficient process for organic synthesis in aqueous media based on a direct ohmic heating reactor is described. Four representative organic transformations, a Diels-Alder cycloaddition, a nucleophilic substitution, an N-alkylation and a Suzuki cross-coupling reaction, were performed using this process. The results, when compared with those obtained under conventional external heating (oil bath) and microwave heating, showed that ohmic reactor allows faster and more uniform heating and an induced increase of dynamics/mobility of charged species leading in several cases to higher reaction yields and shorter reaction times.
TypeArticle
URIhttp://hdl.handle.net/1822/25526
DOI10.1039/c3gc36881e
ISSN1463-9270
e-ISSN1463-9262
Peer-Reviewedyes
AccessRestricted access (UMinho)
Appears in Collections:CEB - Publicações em Revistas/Séries Internacionais / Publications in International Journals/Series

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