Utilize este identificador para referenciar este registo: http://hdl.handle.net/1822/22057

TítuloDiastereo-selectivity in diels–alder cycloadditions of erythrose benzylidene-acetal 1,3-Butadienes with maleimides
Autor(es)Salgueiro, D. A. L.
Duarte, Vera C. M.
Sousa, Cristina
Alves, M. José
Fortes, A. Gil
Palavras-chavemaleimides
D-erythrose benzylidene-acetal 1,3-butadiene
Diels-Alder cycloaddition
selectivity
Data2012
EditoraGeorg Thieme Verlag
RevistaSynlett
Resumo(s)Maleimides were combined with D-erythrose benzylidene-acetal 1,3-butadienes 1 and 2 to study the facial selectivity of the Diels-Alder cycloadditions. The selectivity was found to be from moderate to good. The reaction diastereotopicity can be reversed with the temperature. Simultaneous coordination of diene 1, having a free hydroxyl group, and maleimide 3 to a chiral bimetallic Lewis acid catalyst (LACASA-DA reaction) occurs with complete diastereo-control to give a single adduct, using an extra chiral inductor either R- or S-BINOL.
Tipoarticle
URIhttp://hdl.handle.net/1822/22057
DOI10.1055/s-0031-1289785
ISSN0936-5214
Arbitragem científicayes
AcessoopenAccess
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