Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/1845
Título: | Cycloaddition of methyl 2-(2,6-dichorophenyl)-2H-azirine-3-carboxylate to electron rich 2-azadienes |
Autor(es): | Alves, M. José Durães, M. Miguel Fortes, A. Gil |
Palavras-chave: | 2-azadienes 2H-azirines Diels-alder reactions |
Data: | 2003 |
Editora: | Elsevier |
Revista: | Tetrahedron Letters |
Citação: | Alves, M. J., Durães, M. M., & Gil Fortes, A. (2003, June). Cycloaddition of methyl 2-(2,6-dichorophenyl)-2H-azirine-3-carboxylate to electron-rich 2-azadienes. Tetrahedron Letters. Elsevier BV. http://doi.org/10.1016/s0040-4039(03)01138-9 |
Resumo(s): | Tert-Butyldimethylsililoxy-2-aza-1,3-butadienes react with 2H-azirine 3 leading to Diels-Alder cycloadducts in moderate yields. The reactions are endo- and regio- selective with the azirine being added by its less hindered face. There is only one product in the case of 1b, 4b. There are two isomers (4 and 5) from 1a, 1c and 1d. A different result was obtained with the diene 1e. Diene 1e formed products 4e and 8. Some of compounds 4 and 5 have been hydrolysed leading to functionalized aziridines 7. Compound 8 gave aziridine 9. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/1845 |
DOI: | 10.1016/S0040-4039(03)01138-9 |
ISSN: | 0040-4039 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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MigPaper-vers2.pdf | 63,15 kB | Adobe PDF | Ver/Abrir |