Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/1845

TitleCycloaddition of methyl 2-(2,6-dichorophenyl)-2H-azirine-3-carboxylate to electron rich 2-azadienes
Author(s)Alves, M. José
Durães, M. Miguel
Fortes, A. Gil
Keywords2-azadienes
2H-azirines
Diels-alder reactions
Issue date2003
PublisherElsevier
JournalTetrahedron Letters
Citation"Tetrahedron letters". 44 (2003) 5079-5082.
Abstract(s)Tert-Butyldimethylsililoxy-2-aza-1,3-butadienes react with 2H-azirine 3 leading to Diels-Alder cycloadducts in moderate yields. The reactions are endo- and regio- selective with the azirine being added by its less hindered face. There is only one product in the case of 1b, 4b. There are two isomers (4 and 5) from 1a, 1c and 1d. A different result was obtained with the diene 1e. Diene 1e formed products 4e and 8. Some of compounds 4 and 5 have been hydrolysed leading to functionalized aziridines 7. Compound 8 gave aziridine 9.
TypeArticle
URIhttp://hdl.handle.net/1822/1845
DOI10.1016/S0040-4039(03)01138-9
ISSN0040-4039
Peer-Reviewedyes
AccessOpen access
Appears in Collections:CDQuim - Artigos (Papers)

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