Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/1843

TitleStereoselective cycloaddition of 1-glucosyl-1,3-butadienes with tert-butyl 2H-azirine-3-carboxylate, glyoxylates and imines
Author(s)Alves, M. José
Almeida, I. G.
Fortes, A. Gil
Freitas, A. P.
KeywordsCycloaddition
1,3-butadienes
2H-azirines
Glyoxylates
Imines
Issue date2003
PublisherElsevier
JournalTetrahedron Letters
Citation"Tetrahedron letters". 44 (2003) 6561-6565.
Abstract(s)Glucosyl dienes 1 have been reacted with the achiral 2H-azirine 4 and with glyoxylates, forming fused structures of type 5 and disaccharide-like compounds 7 with good to excellent selectivity. Glucosyl dienes 1 participated as dienophiles in reactions with Schiff bases derived from anilines forming isoquinolines 10 and 11. The diastereoselectivity of this reaction is poor.
TypeArticle
URIhttp://hdl.handle.net/1822/1843
DOI10.1016/S0040-4039(03)01696-4
ISSN0040-4039
Peer-Reviewedyes
AccessOpen access
Appears in Collections:CDQuim - Artigos (Papers)

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