Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/17304

TitleCharacterisation of enzymatically oxidised lignosulfonates and their application on lignocellulosic fabrics
Author(s)Kim, Suyeon
Silva, Carla Manuela Pereira Marinho da
Zille, Andrea
López, C.
Evtuguin, D. V.
Paulo, Artur Cavaco
KeywordsFTIR
Gel permeation chromatography (GPC)
Laccase
Lignosulfonates
UV-visible spectroscopy
Issue date2009
PublisherWiley
JournalPolymer International
Abstract(s)The ‘double function’ of laccase, from the ascomycete Myceliophthora, to depolymerise/polymerise lignin was studied in this work. A lignosulfonate (LS) compound was oxidised by enzymatic action and several techniques were applied to measure the polymeric changes obtained. This study was focused on the attachment level of the oxidised LS at the flax surface. RESULTS: Modified solutions were studied in terms of surface charge. Zeta potential values obtained showed an increase of polymerisation after several days of incubation. The change in molecular weight after LS polymerisation was detected using gel permeation chromatography. An increase of 1700 Da was achieved. Fourier transform infrared and UV-visible spectroscopy techniques were applied and the results showed an increase of the degree of polymerisation. The colour strength of flax fabrics incubated with oxidised LS solutions was also measured and an increase of K/S (K, absorption coefficient; S, scattering coefficient) after enzymatic oxidation was observed. CONCLUSION: The oxidised lignin products obtained show good potential for use in natural surface modification of textile materials containing flavonoids. These findings have important practical implications for lignocellulosic fibre coloration, where new polymers can replace harsh chemicals in the textile industry. Copyright © 2009 Society of Chemical Industry
TypeArticle
URIhttp://hdl.handle.net/1822/17304
DOI10.1002/pi.2600
ISSN1097-0126
Peer-Reviewedyes
AccessOpen access
Appears in Collections:DET/2C2T - Artigos em revistas internacionais com arbitragem científica

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