Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/14262

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dc.contributor.authorMoreira, J. Agostinho-
dc.contributor.authorAlmeida, A.-
dc.contributor.authorVieira, L. G.-
dc.contributor.authorRibeiro, J. L.-
dc.contributor.authorChaves, M. R.-
dc.contributor.authorSantos, M. L.-
dc.contributor.authorKlöepperpieper, A.-
dc.date.accessioned2011-11-11T14:46:03Z-
dc.date.available2011-11-11T14:46:03Z-
dc.date.issued2005-
dc.identifier.issn1098-0121por
dc.identifier.urihttp://hdl.handle.net/1822/14262-
dc.description.abstractThis work reports a study of the temperature dependence 290–20 K of the lattice dynamics of glycinium phosphite obtained from polarized Raman spectroscopy X yy Z and infrared reflectivity E b measurements. The loss of the inversion center at the para-ferroelectric phase transition gives rise to the activation of additional infrared and Raman bands. The oscillator strength of some infrared lattice modes that arise in the ferroelectric phase can be correlated with the temperature dependence of the order parameter of the phase transition. Several anomalies, which have been detected in the temperature dependence of the frequency and of the damping coefficient of some external and internal modes of the phosphite group, are described by a theoretical model that takes into account the coupling between proton pseudo-spins and phonons. The results obtained indicate that the phosphite group behavior affects the characteristic time of the proton flipping motion and reflects the long range ferroelectric order in glycinium phosphite.eng
dc.language.isoengpor
dc.publisherAmerican Physical Societypor
dc.rightsrestrictedAccesspor
dc.titleCoupling between proton pseudo-spins and normal modes in ferroelectric glycinium phosphitepor
dc.typearticlepor
dc.peerreviewedyespor
sdum.publicationstatuspublishedpor
oaire.citationStartPage094111-1por
oaire.citationEndPage094111-11por
oaire.citationIssue9por
oaire.citationVolume72por
dc.identifier.essn1550-235X-
dc.identifier.doi10.1103/PhysRevB.72.094111por
dc.subject.wosScience & Technologypor
sdum.journalPhysical Review B: Condensed Matter and Materials Physicspor
Appears in Collections:CDF - FCD - Artigos/Papers (with refereeing)

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