Please use this identifier to cite or link to this item: http://hdl.handle.net/1822/1336

TitleSolvent extraction aplied to the recovery of heavy metals from galvanic sludges
Author(s)Silva, João Eudes da
Paiva, A. P.
Soares, Delfim
Labrincha, J. A.
Castro, F.
KeywordsGalvanic sludge
Metals extraction
D2EHPA
Cyanex 272
Solventes
Extracção
Metais pesados
Hidrometalurgia
Resíduos
Issue date2005
PublisherElsevier
JournalJournal of Hazardous Materials
Citation"Journal of hazardous materials". ISSN 0304-3894. 120:1-3 (2005) 113-118.
Abstract(s)In this study, a hydrometallurgical treatment involving the solvent extraction and recovery of some heavy metals from a sulphuric acid leach solution of galvanic sludge, using di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and bis-(2,4,4- trimethylpentyl)-phosphinic acid (Cyanex 272), both diluted in kerosene, has been investigated. The preliminary tests revealed the necessity to remove other metal species than zinc and nickel, contained in the leach solution, and therefore, processes to cement copper and precipitate chromium were then applied to finally obtain a Zn and Ni pregnant solution prior to solvent extraction. For the experimental conditions studied, Cyanex 272 showed a good recovery of Zn after the stripping stage using H2SO4, but D2EHPA effectively promoted a higher Zn extraction than Cyanex 272 did. The dependence of the solvent extraction method on variables such as pH, contact time and concentration of extractant, as well as the effect of different concentrations of sulphuric acid on stripping, are discussed. The discussion also includes the previous conditions developed to separate the main interfering metallic species from the leach solution in order to improve the extraction and recovery of zinc by solvent extraction. The final objective has been to achieve a solution as pure as possible to recover nickel sulphate.
Estudou-se o desenvolvimento de um processo metalúrgico para a extracção de metais a partir de lamas galvânicas, passando por fases e extracção com solventes orgânicos
TypeArticle
URIhttp://hdl.handle.net/1822/1336
DOI10.1016/j.jhazmat.2004.12.008
ISSN0304-3894
Publisher versionhttp://www.sciencedirect.com/science/journal/03043894
Peer-Reviewedyes
AccessOpen access
Appears in Collections:DEM - Artigos em revistas de circulação internacional com arbitragem científica

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