Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/13271
Título: | Role of ultraviolet absorbers (UVA) and hindered amine light stabilizers (HALS) in ABS stabilization |
Autor(es): | Santos, R. M. Botelho, Gabriela Machado, A. V. |
Palavras-chave: | ABS Light stabilizers Yellowing Chemical modifications |
Data: | 2010 |
Editora: | Trans Tech Publications Ltd |
Revista: | Materials Science Forum |
Resumo(s): | The present work evaluates the combination effect of hindered amine light stabilizers (HALS) and ultraviolet absorbers (UVA) on the ultraviolet (UV) stability of acrylonitrilebutadiene- styrene (ABS). Thus, two types of light stabilizers, Tinuvin P and Chimassorb 119 FL, were used to improve the ABS endurance against UV. Stabilized ABS samples were submitted to accelerated weathering in a Xenontest 150 S chamber, according to standard methods, in order to predict copolymer lifetime within a commercially acceptable time period. Infrared spectroscopy with attenuated total reflectance accessory (FTIR-ATR) was used to follow chemical modifications that occur on the material surface as a consequence of degradation process. While non-stabilized ABS samples loose the butadiene component in the first 22 h of exposure, in stabilized samples submitted to same accelerated conditions this component only disappears after 150 h of exposure. Non-stabilized and stabilized ABS samples present a similar yellowing behavior, a gradually increase with exposure time. Nevertheless, as expected, color modifications are less pronounced for stabilized ABS samples. The results obtained suggest that a better performance was achieved for stabilized ABS samples with Tinuvin P and Chimassorb 119 FL, which is very important to extend the copolymer lifetime. |
Tipo: | Artigo em ata de conferência |
URI: | https://hdl.handle.net/1822/13271 |
DOI: | 10.4028/www.scientific.net/MSF.636-637.772 |
ISSN: | 0255-5476 |
Arbitragem científica: | yes |
Acesso: | Acesso restrito UMinho |
Aparece nas coleções: | IPC - Artigos em revistas científicas internacionais com arbitragem |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
47.AVM.pdf Acesso restrito! | 271,66 kB | Adobe PDF | Ver/Abrir |